Table 2.
Variation of temperature and pressure.[a]
|
Entry |
c cat [mol m−3] |
c TPPTS [mol m−3] |
T [°C] |
p [MPa] |
X [%] |
Y Ald [%] |
S Ald [%] |
l/b ratio |
TOF[b] [h−1] |
STY [kg m−3 h−1] |
|---|---|---|---|---|---|---|---|---|---|---|
|
2.1 |
0.5 |
5 |
100 |
8 |
62 |
32 |
52 |
2.6 |
2057 |
58.5 |
|
2.2 |
0.5 |
5 |
120 |
8 |
92 |
41 |
45 |
1.5 |
2631 |
74.8 |
|
2.3 |
0.5 |
5 |
140 |
8 |
86 |
24 |
28 |
0.9 |
1502 |
42.7 |
|
2.4 |
0.5 |
5 |
80 |
10 |
17 |
13 |
76 |
2.0 |
818 |
23.3 |
|
2.5 |
0.5 |
5 |
80 |
12 |
15 |
12 |
79 |
1.9 |
738 |
21.0 |
[a] Conditions: t=1.5 h, pH=5.5, ϕorg=0.6, V R=100 mL, n=1725 min−1. [b] TOF=n prod/(n Rh×t R).