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. Author manuscript; available in PMC: 2023 Jul 25.
Published in final edited form as: Angew Chem Int Ed Engl. 2022 Jun 2;61(30):e202204570. doi: 10.1002/anie.202204570

Scheme 1.

Scheme 1.

Synthesis of complex 1 from FeCl2 and [PNP][SSNO]. Solid state structure of [Fe(NO)2(S5)] in 1. Ellipsoids are shown at 50% probability levels. Blue, red, orange, and yellow ellipsoids represent N, O, Fe, and S atoms, respectively. The [PNP]+ cation is omitted for clarity.