Table 1.

Energy involved in the interaction of [trans‐(CF₃)₂AgX₂]⁻ with an additional X⁻ ligand in the indicated solvent.^[a]

	X=F		X=Cl		X=Br		X=I
solvent	ΔG	ΔH	ΔG	ΔH	ΔG	ΔH	ΔG	ΔH
Me2CO	4.4	−3.2	1.6	−7.5	−1.2	−9.5	−0.4	−8.0
MeCN	4.1	−4.8	0.3	−8.7	−2.4	−10.7	−1.0	−9.2

[a] Values [kcal mol⁻¹] calculated at the DFT/M06/Def2‐TZVPD level of theory.