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. 2022 Jul 20;12:12431. doi: 10.1038/s41598-022-16753-8

Table 3.

Kinetics constants for the adsorption of dyes by ZPBIF-1 (Contact time = 20 min, Tem = 25–65 °C, Adsorbent mass = 0. 08 g/L, Initial concertation 50 and 250 mg/L, Stirring = 400 rpm and pH = 2).

Acid Red 88 Basic Violet 14 Basic blue 54 Congo red
Pseudo-first-order model
C0 (mg/L) 50 250 50 250 50 250 50 250
qe,exp(mg/g) 61.87 307.55 62.18 310.30 59.37 281.25 62.41 311.87
qe,cal (mg/g) 55.63 370.59 53.57 183.71 61.90 252.29 59.24 270.20
K1/(min) 0.1376 0.3894 0.1704 0.6632 0.3614 0.2998 0.4054 0.5918
R2 0.9333 0.9732 0.9160 0.9304 0.9983 0.9845 0.9981 0.9930
First-order model
C0 64.80 185.04 61.75 107.66 34.80 183.60 36.88 102.53
K1 0.2066 0.2208 0.2384 0.2548 0.1554 0.1185 0.3401 0.3329
R2 0.8630 0.9301 0.888 0.7745 0.8722 0.8470 0.9774 0.8386
Pseudo-second-order model
qe,cal (mg/g) 59.88 312.5 60.97 312.5 58.82 277.77 62.50 312.5
K2 (g/min mg) 0.0228 0.0256 0.0389 0 0.0741 0.0648 0.3657 1.024
R2 0.9798 0.9994 0.9926 1 0.9979 0.9999 1 1
Second-order model
C0 2.94 89.28 1.44 10.39 28.01 142.85 0.42 28.32
K2 0.0806 0.0138 0.1575 0.029 0.0199 0.0018 0.7185 0.1314
R2 0.5178 0.8610 0.5106 0.7872 0.9682 0.9310 0.7514 0.9737
Intra-particle diffusion model
Kp (g/min.mg) 7.6325 10.3320 4.6708 0.0381 1.4859 6.9672 0.6844 0.3658
C (mg/g) 26.29 263.53 40.30 310.13 52.95 250.35 59.45 310.42
R2 0.8209 0.7934 0.7896 0.9977 0.8812 0.9930 0.8846 0.8637
Elovich constants
R2 0.7865 0.8273 0.7554 0.9916 0.9063 0.9984 0.9094 0.892
α (mg/g min) 50.6321840032

5,454,780.13

12,788

508.2847556925 169,642,386.81368 1,169,223,763.5818 3.06752219E + 190 1.36661039E + 191
ß (g/mg) 0.070 0.050 0.115 13.90 0.350 0.075 0.761 1.421

The raw data for this table is provided in the Supplementary file 2.