Table 3.
Kinetics constants for the adsorption of dyes by ZPBIF-1 (Contact time = 20 min, Tem = 25–65 °C, Adsorbent mass = 0. 08 g/L, Initial concertation 50 and 250 mg/L, Stirring = 400 rpm and pH = 2).
| Acid Red 88 | Basic Violet 14 | Basic blue 54 | Congo red | |||||
|---|---|---|---|---|---|---|---|---|
| Pseudo-first-order model | ||||||||
| C0 (mg/L) | 50 | 250 | 50 | 250 | 50 | 250 | 50 | 250 |
| qe,exp(mg/g) | 61.87 | 307.55 | 62.18 | 310.30 | 59.37 | 281.25 | 62.41 | 311.87 |
| qe,cal (mg/g) | 55.63 | 370.59 | 53.57 | 183.71 | 61.90 | 252.29 | 59.24 | 270.20 |
| K1/(min) | 0.1376 | 0.3894 | 0.1704 | 0.6632 | 0.3614 | 0.2998 | 0.4054 | 0.5918 |
| R2 | 0.9333 | 0.9732 | 0.9160 | 0.9304 | 0.9983 | 0.9845 | 0.9981 | 0.9930 |
| First-order model | ||||||||
| C0 | 64.80 | 185.04 | 61.75 | 107.66 | 34.80 | 183.60 | 36.88 | 102.53 |
| K1 | 0.2066 | 0.2208 | 0.2384 | 0.2548 | 0.1554 | 0.1185 | 0.3401 | 0.3329 |
| R2 | 0.8630 | 0.9301 | 0.888 | 0.7745 | 0.8722 | 0.8470 | 0.9774 | 0.8386 |
| Pseudo-second-order model | ||||||||
| qe,cal (mg/g) | 59.88 | 312.5 | 60.97 | 312.5 | 58.82 | 277.77 | 62.50 | 312.5 |
| K2 (g/min mg) | 0.0228 | 0.0256 | 0.0389 | 0 | 0.0741 | 0.0648 | 0.3657 | 1.024 |
| R2 | 0.9798 | 0.9994 | 0.9926 | 1 | 0.9979 | 0.9999 | 1 | 1 |
| Second-order model | ||||||||
| C0 | 2.94 | 89.28 | 1.44 | 10.39 | 28.01 | 142.85 | 0.42 | 28.32 |
| K2 | 0.0806 | 0.0138 | 0.1575 | 0.029 | 0.0199 | 0.0018 | 0.7185 | 0.1314 |
| R2 | 0.5178 | 0.8610 | 0.5106 | 0.7872 | 0.9682 | 0.9310 | 0.7514 | 0.9737 |
| Intra-particle diffusion model | ||||||||
| Kp (g/min.mg) | 7.6325 | 10.3320 | 4.6708 | 0.0381 | 1.4859 | 6.9672 | 0.6844 | 0.3658 |
| C (mg/g) | 26.29 | 263.53 | 40.30 | 310.13 | 52.95 | 250.35 | 59.45 | 310.42 |
| R2 | 0.8209 | 0.7934 | 0.7896 | 0.9977 | 0.8812 | 0.9930 | 0.8846 | 0.8637 |
| Elovich constants | ||||||||
| R2 | 0.7865 | 0.8273 | 0.7554 | 0.9916 | 0.9063 | 0.9984 | 0.9094 | 0.892 |
| α (mg/g min) | 50.6321840032 |
5,454,780.13 12,788 |
508.2847556925 | ∞ | 169,642,386.81368 | 1,169,223,763.5818 | 3.06752219E + 190 | 1.36661039E + 191 |
| ß (g/mg) | 0.070 | 0.050 | 0.115 | 13.90 | 0.350 | 0.075 | 0.761 | 1.421 |
The raw data for this table is provided in the Supplementary file 2.