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. 2021 Dec 21;61(6):e202114191. doi: 10.1002/anie.202114191

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© 2021 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH

This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.

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Different views of the P2₁3 unit cell of AsN (As atoms in violet and N atoms in light blue) in the ball‐stick representation mode along different crystallographic directions: [100] (A and B), [110] (C and D), one of the C ₃ axis directed along [111] (E and F). The shaded polyhedra indicate the AsN₃ (left) and NAs₃ (right) trigonal pyramids mentioned in the text and highlighted on the top of the Figure. Data refer to AsN at 35.6 GPa and 293 K.