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Selected regions of the AsN unit cell showing different As4 cage‐like tetrahedral structures: A As4‐As01‐As01‐As01, B As03‐As02‐As02‐As02, C As04‐As02‐As02‐As02 and As03‐As01‐As01‐As01. Their arrangement along one of the C 3 axes, coincident with the [111] direction of the cell diagonal, is shown in (D) and (E). The structural motifs shown in this Figure refer to AsN at 35.6 GPa and 293 K.
