. Author manuscript; available in PMC: 2023 Jul 13.

Published in final edited form as: J Am Chem Soc. 2022 Jun 30;144(27):12229–12246. doi: 10.1021/jacs.2c03235

Table 3.

Electron-Primed Photoredox Studies.


Entry	Conditions	Yield of 2a^a
1	456 nm LED lamp	65%
2	456 nm LED lamp, no QDs	0%
3	no light	0%
4	no light, 40 °C	0%
5	525 nm LED lamp^b	9%
6	650 nm LED lamp	0%

Corrected GC yield for reactions with 0.2 mmol 1a. Average power consumption of LED lamps was 50 W. See Supporting Information for experimental details.

500 nm long-pass filter employed to prevent overlap with neutral exciton.