Table 2.

Chiroptical properties of (R)‐6 and (S)‐6

	g abs [a]	g lum [b]	B CPL [c] [M−1 cm−1]	${\left[\alpha \right]}_{589}^{20}$ [d] [°]
(R)‐6	−8×10−4	−8×10−4	21.9	+1192
(S)‐6	+8×10−4	+8×10−4	21.9	−1189

[a] g _abs=Δϵ/ϵ, in CH₂Cl₂ (2×10⁻⁴ M, 293 K) calculated at 451 nm. [b] g _lum=2(I _L−I _R)/(I _L+I _R), in CH₂Cl₂ (4.5×10⁻⁵ M, 293 K), excited at λ _ex=365 nm. [c] Brightness for CPL ^[15] B _CPL=ϵ _λ ×Φ _PL×|g _lum|/2 at λ _ex=365 nm. [d] ${\left[\alpha \right]}_{589}^{20}$ =α _obs/(cl), in CHCl₃ (0.500 g mL⁻¹, 293 K).