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. 2022 Feb 23;61(16):e202117455. doi: 10.1002/anie.202117455

Figure 1.

Figure 1

Supraparticles from uniform, polyhedral MOF building blocks. a) FESEM of monodisperse rhombic dodecahedron (RD‐ZIF‐8), truncated rhombic dodecahedron (TRD‐ZIF‐8), cube (C‐ZIF‐8) and octahedron (O‐UiO‐66) particles (left to right). b, c) Monodisperse TRD‐ZIF‐8 supraparticles prepared by emulsifying the MOF particle dispersion using droplet‐based microfluidics. d) FESEM (from left to right) of RD‐ZIF‐8, TRD‐ZIF‐8, C‐ZIF‐8 and O‐UiO‐66 supraparticles, exhibiting ordered surfaces and characteristic packings. e) Snapshots of Monte Carlo simulations with polyhedra in spherical confinement.