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. Author manuscript; available in PMC: 2022 Aug 1.
Published in final edited form as: Chem Rev. 2022 Jan 25;122(14):12207–12243. doi: 10.1021/acs.chemrev.1c00915

Figure 24.

Figure 24.

(A) DR-UV-vis data from Fe-*BEA tracking the conversion of α-Fe(II) in (green trace) into α-N2O (red trace). (B) DR-UV-vis data tracking the subsequent conversion of α-N2O (red trace) into α-O (blue trace). (C) Comparison of experimental data from α-N2O to predicted values from DFT models of sites with N-versus O-bound N2O ligands. Adapted from ref 77 with permission. Copyright 2020 Nature Publishing Group.