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. Author manuscript; available in PMC: 2022 Aug 1.
Published in final edited form as: Chem Rev. 2022 Jan 25;122(14):12207–12243. doi: 10.1021/acs.chemrev.1c00915

Table 1.

Binding motifs of N2O with a binuclear Cu(I) center, the Cu···Cu distances of those motifs, and the activation energy for the formation of those motifs.

binding modes Cu-Cu distance activation energy
graphic file with name nihms-1799827-t0002.jpg 3.45 Å 2 kcal/mol
graphic file with name nihms-1799827-t0003.jpg 4.62 Å > 60 kcal/mol
graphic file with name nihms-1799827-t0004.jpg 5.36 Å 5 kcal/mol