Table 2.

Summary of different synthetic strategies for MOF composites with ECL properties.

MOF Composites	Ligands	Metal Source	Ref.
In situ synthesis
MIL-101(Al)–NH2	NH2-BDC	AlCl3	[46]
IRMOF-3	NH2-BDC	Zn(NO3)2	[47]
Ru(bpy)32+/NH2-UiO-66	NH2-BDC	ZrCl4	[48]
Fe(III)-MIL-88B-NH2	NH2-BDC	FeCl3	[49]
UiO-67	BPDC	ZrCl4	[50]
GSH-Au NCS@ZIF-8	2-MI	Zn(NO3)2	[51]
Zinc Oxalate MOFs	Oxalic acid	Zn(NO3)2	[52]
Post-synthesis modifications
Ru-MOF-5 NFs	PTA	Zn(NO3)2	[53]
Cu/Co-MOF	2-MI	Co(NO3)2, Cu(NO3)2	[54]
HH-Ru-UiO66-NH2	NH2-BDC	ZrCl4	[55]
Co-Ni/MOF	2-MI	Co(NO3)2, Ni (NO3)2	[56]
AgNPs@Ru-MOF	NH2-BDC	ZrCl4	[57]
g-C3N4@NH2-MIL-101	NH2-BDC	FeCl3·6H2O	[58]
Zn-Bp-MOFs	H3BTC,4,4-dipyridyl	Zn(NO3)2	[59]
Ru-PCN-777	H3TATB	ZrOCl2	[60]
Self-luminous MOFs
Eu-MOFs	5-bop	EuCl3	[61]
RuMOF NS	[Ru(H2dcbpy)3]Cl2	Zn(NO3)2	[62]
Eu-MOF	[Ru(H2dcbpy)3]Cl2	Eu(NO3)3	[63]
Zr-TCBPE-MOF	H4TCBPE	ZrCl4	[64]
Hf-TCBPE	H4TCBPE	HfCl4	[65]
Zr12-adb	H2adb	ZrCl4	[66]
Tb-Cu-PA MOF	IPA	TbCl3, Cu(NO3)2	[67]
Zn-PTC	PTC	Zn(CH3COO)2	[68]
Ru@Zr12-BPDC	BPDC, H2dcbpy	ZrCl4	[69]
Cu:Tb-MOF	IPA	TbCl3, Cu(NO3)2	[70]
UMV-Ce-MOF	H3BTC	Ce(NO3)3	[71]
PTP/Eu MOF	H3BTC	Eu(NO3)3	[72]
Ce-TCPP-LMOF	TCPP	Ce(NO3)3	[73]
Zn-MOF	Hcptpy	ZnSO4	[74]