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. 2022 Jul 25;12:12009. doi: 10.1038/s41598-022-16156-9

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© The Author(s) 2022

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.

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Effect of fluoroalkyl side chains on the structure and viscoelastic properties of the materials. (a) Experimental and simulated small-angle X-ray scattering patterns of the fluorinated elastomers. Simulations were performed according to the Yarusso–Cooper model⁵¹. (b) Differential scanning calorimetry traces of the fluorinated elastomers. The glass transition temperature (T_g) of each polymer is indicated with an arrow. (c) Effect of fluoroalkyl side chains on the temperature dependence of the storage modulus (E') and tanδ for the indicated polymers. (d) Temperature dependence of E' and tanδ for fluorinated poly(ethyl acrylate-random-methyl acrylate) PEMAxFy having different fluoroalkyl side chain lengths.