Table 1.

Catalytic and kinetic data for complexes 1–5.

Catalyst	TOF [s−1][a]	Reaction order[b]	TOF [s−1][c]	E III/II [V vs. NHE][d]	E IV/III [V vs. NHE][d]	E V/IV [V vs. NHE][d]	KIE[e]
1	1.3	0.96	0.03	0.73	/	1.18	1.16
2	2.3	0.99	0.09	0.73	0.95	1.14	1.07
3	5.7	1.29	0.28	0.74	0.99	1.17	1.71
4	34.1	1.01	0.31	0.77	0.95	1.14	1.31
5	166.6 [21]	2 [21]	0.68	0.77	0.99	1.17	1.66

[a] TOF stands for turnover frequency, values for 1–4 extracted from Ce^IV‐driven water oxidation activities at pH 1, [cat]=0.16 mM; [b] values of reaction order in catalysts for 1–4 extracted from Ce^IV‐driven water oxidation activities at pH 1. [c] TOF values extracted from CV according to equation 1; [d] potential measured in 0.1 M NaH₂PO₄ aqueous solution with 30 % CF₃CH₂OH; [e] KIE stands for kinetic isotope effect, values obtained electrochemically in 0.1 M NaH₂PO₄ aqueous solution with 30 % CF₃CH₂OH.