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. Author manuscript; available in PMC: 2022 Jul 26.
Published in final edited form as: Science. 2018 Sep 28;361(6409):1369–1373. doi: 10.1126/science.aat2117

Figure 4. Experiments to probe reaction mechanism.

Figure 4.

(A) Aminoarylation with (Z)-anethole (28). (B) Tracking reaction progress for aminoarylation with (Z)-anethole (28) (▲ = 2, ■ = (Z)-anethole, ♦ = 9, ■ = (E)-anethole). (C) Determination of the photostationary state for anethole isomers catalyzed by 3. (D) Favored and disfavored conformations for intermediate III.