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. 2022 Jul 19;12(7):665. doi: 10.3390/metabo12070665

Figure 1.

Figure 1

Analytical features of tramadol. (A) Extracted ion chromatogram of urine extract at m/z 264.1954 corresponding to [M + H]+ ion of tramadol. (B) Mass spectra of tramadol and its corresponding isotopic pattern. (C) MS/MS spectra of [M + H]+ ion of tramadol. Inspection of the MS/MS spectra allow for the identification of an intense peak at m/z 58.0660 corresponding to a methyl aziridium ion, indicative of the dimethyl amino radical of tramadol.