Table 9.
Photophysical and polymerization data of the photo initiators BcP‐6 to BcH‐5.
|
Compound |
λmax [nm] |
Φfl |
σTPA [GM] |
FW [mW] |
|---|---|---|---|---|
|
BcP‐10 |
362/502[a] |
0.011 |
600[d] |
7–48 [g] |
|
BA740 |
– |
0.064 |
177[e] |
50–180[h] |
|
PBDA |
473.5[c] |
0.108 |
410[f] |
0.13–9.31 |
|
BDEA |
487[c] |
0.141 |
465[f] |
0.09–5.84 |
[a] Measured in dichloromethane, [b] measured in chloroform, [c] measured in DMSO, [d] measured via Z‐scan at 725 nm, [e] measured via Z‐scan, [f] measured via TPEF in range of 750 to 880 nm, [g] FW at a writing speed of 2 mm/s and [h] FW at a writing speed of 3 mm/s.