Table 1. Decomposition Temperatures and Surface Areas of Various Reported MIL-101(M) and NH2-MIL-101(M) MOFs, Together with Those of NH2-MIL-101(TiIII, Al) Described in This Work.
| decomposition temperature (°C) |
surface area (m2/g) |
||||
|---|---|---|---|---|---|
| MOF | TGA | VT-PXRD | BET | Langmuir | reference |
| MIL-101(Cr) | n/a | n/a | 2800–4230 | n/a | (12) |
| ∼350 | n/a | 2134 | n/a | (54) | |
| NH2-MIL-101(Cr) | 250 | n/a | 2070 | n/a | (55) |
| MIL-101(Fe) | n/a | n/a | 2123 | n/a | (56) |
| n/a | n/a | 1420 | n/a | (57) | |
| NH2-MIL-101(Fe) | n/a | n/a | 2572 | n/a | (56) |
| MIL-101(V) | 300 | n/a | 3600 | 5700 | (19) |
| MIL-101(Sc) | 450 | n/a | 155–640 | n/a | (58) |
| NH2-MIL-101(Sc) | 300a | n/a | n/aa | n/aa | (57) |
| NH2-MIL-101(Al) | n/a | ∼150 | 3440 | 4799 | this work |
| n/a | n/a | 2074 | n/a | (56) | |
| >377 | n/a | 2100 | n/a | (16) | |
| >500 | n/a | 2530 | n/a | (53) | |
| MIL-101(TiIII) | n/a | n/a | 2970 | 3890–4440 | (27) |
| n/a | n/a | 3285 | 4360 | (28) | |
| NH2-MIL-101(TiIII, Al) | n/a | 200 | 2024–2146 | 2792–2966 | this work |
a
Cannot be activated, structural transformation to NH2-MIL-88(Sc) upon heating.