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. 2022 Apr 1;51(8):3243–3262. doi: 10.1039/d0cs01192d

Summary of iodine adsorption in MOFs via solution-based processes.

MOF Solution media BET surface area (m2 g−1) Pore volume (cm3 g−1) Iodine uptake (g g−1) Ref.
{[WS4Cu4(4,4′-bpy)4][WS4Cu4I4(4,4′-bpy)2]}b CCl4 0.20 95
[Cd3(BTC)2(TIB)2]nb Hexane 0.16 123
[Cd(L1)2(ClO4)2]b Hexane 0.19 98
TMU-16b Hexane 0.22 130
TMU-16-NH2b Hexane 1.28 130
[Zn3(BTC)2(TIB)2]nb Hexane 0.21 123
[Zn3(L2)22-OH)2]nb Hexane 0.28 138
[Zn3(L3)22-OH)2]nb Hexane 0.26 138
JLU-Liu14b Ethanol 0.16 139
[CuII(btz)]nb Cyclohexane 0.47 97
JLU-Liu32b Cyclohexane 0.29 130
[Tb3(Cu4I4)3(ina)9]nb Cyclohexane 0.28 73
TMU-15b Cyclohexane 1.30 59
[Zn7(L4)3]n·[Zn5(L4)3]nb Cyclohexane 0.46 140
[Cd(bdc)(4-bpmh)]n Hexane 36 0.09 0.15 141
[Cd(2-NH2bdc)(4-bpmh)]n Hexane 30 0.13 0.28 141
Cu2TMBD Hexane 197 0.15 0.18 142
IFMC-10 Hexane 185 0.09 0.04 143
IFMC-15 Hexane 138 0.07 1.10 144
BOF-1 DMSO/H2O 138c 0.09 0.93 81
Cu(H2L5) Cyclohexane 646 0.35 0.66 145
[Co(ebic)2]n Cyclohexane 42c 0.07 0.75 146
MIL-53-NH2(Al) Cyclohexane 735 0.35 0.18 68
MIL-101-NH2(Al) Cyclohexane 2100 1.12 0.31 68
JLU-Liu31 Cyclohexane 1700 0.85 0.25 147
UiO-66-PYDC Cyclohexane 1030 0.43 1.25 148
[Zn(ebic)2]n Cyclohexane 50c 0.08 0.74 146
[Zn24-ao2btc)(μ-pbix)2]n Cyclohexane 78 0.07 0.18 131
UiO-66 Cyclohexane 1970 0.898 0.667 148
AgNPs@UiO-66a Cyclohexane 700 0.41 1.260 149
IL@PCN-333(Al)a Hexane 1635 1.40 3.40 86
[DMA][In(TDC)2] Cyclohexane 384.21 0.1 150
Th-TATABb Cyclohexane 0.075 151
{[Zn2(α-bptc)(H2O)4]·(pra)}n Methanol 8.94 0.0221 0.085 152
Ag-MSHC-6a H2O 0.077 62
[Cd(pbica)2]·1.5DMF·2CH3OH Cyclohexane 1073 1.00 136
MIL-125-NH2@chitosan H2O 965.8 0.019 63
MBM H2O 62 0.624 0.88 137
HKUST-1@PES Cyclohexane 1250 0.376 116
HKUST-1@PEI Cyclohexane 990 0.348 116
HKUST-1@ PVDF Cyclohexane 1100 0.225 116
Ag2O-Ag2O3@ZIF-8a H2O 369.9 0.14 0.23 153
Ag@MIL-101a H2O 1045 1.54 2.14 84
a

Study was carried out on a doped MOF.

b

Studies were conducted on a single crystal MOF and no BET surface area or pore volume was reported.

c

Langmuir surface area since BET surface areas of these MOFs were not reported.