Summary of iodine adsorption in MOFs via solution-based processes.
MOF | Solution media | BET surface area (m2 g−1) | Pore volume (cm3 g−1) | Iodine uptake (g g−1) | Ref. |
---|---|---|---|---|---|
{[WS4Cu4(4,4′-bpy)4][WS4Cu4I4(4,4′-bpy)2]}b | CCl4 | — | — | 0.20 | 95 |
[Cd3(BTC)2(TIB)2]nb | Hexane | — | — | 0.16 | 123 |
[Cd(L1)2(ClO4)2]b | Hexane | — | — | 0.19 | 98 |
TMU-16b | Hexane | — | — | 0.22 | 130 |
TMU-16-NH2b | Hexane | — | — | 1.28 | 130 |
[Zn3(BTC)2(TIB)2]nb | Hexane | — | — | 0.21 | 123 |
[Zn3(L2)2(μ2-OH)2]nb | Hexane | — | — | 0.28 | 138 |
[Zn3(L3)2(μ2-OH)2]nb | Hexane | — | — | 0.26 | 138 |
JLU-Liu14b | Ethanol | — | — | 0.16 | 139 |
[CuII(btz)]nb | Cyclohexane | — | — | 0.47 | 97 |
JLU-Liu32b | Cyclohexane | — | — | 0.29 | 130 |
[Tb3(Cu4I4)3(ina)9]nb | Cyclohexane | — | — | 0.28 | 73 |
TMU-15b | Cyclohexane | — | — | 1.30 | 59 |
[Zn7(L4)3]n·[Zn5(L4)3]nb | Cyclohexane | — | — | 0.46 | 140 |
[Cd(bdc)(4-bpmh)]n | Hexane | 36 | 0.09 | 0.15 | 141 |
[Cd(2-NH2bdc)(4-bpmh)]n | Hexane | 30 | 0.13 | 0.28 | 141 |
Cu2TMBD | Hexane | 197 | 0.15 | 0.18 | 142 |
IFMC-10 | Hexane | 185 | 0.09 | 0.04 | 143 |
IFMC-15 | Hexane | 138 | 0.07 | 1.10 | 144 |
BOF-1 | DMSO/H2O | 138c | 0.09 | 0.93 | 81 |
Cu(H2L5) | Cyclohexane | 646 | 0.35 | 0.66 | 145 |
[Co(ebic)2]n | Cyclohexane | 42c | 0.07 | 0.75 | 146 |
MIL-53-NH2(Al) | Cyclohexane | 735 | 0.35 | 0.18 | 68 |
MIL-101-NH2(Al) | Cyclohexane | 2100 | 1.12 | 0.31 | 68 |
JLU-Liu31 | Cyclohexane | 1700 | 0.85 | 0.25 | 147 |
UiO-66-PYDC | Cyclohexane | 1030 | 0.43 | 1.25 | 148 |
[Zn(ebic)2]n | Cyclohexane | 50c | 0.08 | 0.74 | 146 |
[Zn2(μ4-ao2btc)(μ-pbix)2]n | Cyclohexane | 78 | 0.07 | 0.18 | 131 |
UiO-66 | Cyclohexane | 1970 | 0.898 | 0.667 | 148 |
AgNPs@UiO-66a | Cyclohexane | 700 | 0.41 | 1.260 | 149 |
IL@PCN-333(Al)a | Hexane | 1635 | 1.40 | 3.40 | 86 |
[DMA][In(TDC)2] | Cyclohexane | 384.21 | — | 0.1 | 150 |
Th-TATABb | Cyclohexane | — | — | 0.075 | 151 |
{[Zn2(α-bptc)(H2O)4]·(pra)}n | Methanol | 8.94 | 0.0221 | 0.085 | 152 |
Ag-MSHC-6a | H2O | — | — | 0.077 | 62 |
[Cd(pbica)2]·1.5DMF·2CH3OH | Cyclohexane | 1073 | — | 1.00 | 136 |
MIL-125-NH2@chitosan | H2O | 965.8 | — | 0.019 | 63 |
MBM | H2O | 62 | 0.624 | 0.88 | 137 |
HKUST-1@PES | Cyclohexane | 1250 | — | 0.376 | 116 |
HKUST-1@PEI | Cyclohexane | 990 | — | 0.348 | 116 |
HKUST-1@ PVDF | Cyclohexane | 1100 | — | 0.225 | 116 |
Ag2O-Ag2O3@ZIF-8a | H2O | 369.9 | 0.14 | 0.23 | 153 |
Ag@MIL-101a | H2O | 1045 | 1.54 | 2.14 | 84 |
Study was carried out on a doped MOF.
Studies were conducted on a single crystal MOF and no BET surface area or pore volume was reported.
Langmuir surface area since BET surface areas of these MOFs were not reported.