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. 2022 Jul 14;7(29):25822–25836. doi: 10.1021/acsomega.2c03348

Table 5. Adsorption Energy of H2O on Lattice Defects and Defect Clustersa.

lattice defect and cluster n(Pt2+)/n(Ce3+) Ef (eV)
PtCe″-VO·· + H2O 1.59
2CeCe′-VO·· + 2H2O 0.0 0.49
2CeCe′-PtCe″-2VO·· + 3H2O 0.5 0.48
a

n(Pt2+) and n(Ce3+) are the number of lattice defects of Pt2+ and Ce3+.