Skip to main content
. 2022 May 16;51(11):4583–4762. doi: 10.1039/d0cs01079k

Short description of the five types of water electrolysers. Modified from IRENA225.

AWE PEMWE AEMWE SOEC PCCEL
Operating temperature 70–90 °C 50–80 °C 40–60 °C 700–850 °C 300–600 °C
Operating pressure 1–30 bar <70 bar <35 bar 1 bar 1 bar
Electrolyte Potassium hydroxide (KOH) 5–7 mol L−1 PFSA membranes DVB polymer support with KOH or NaHCO3 1 mol L−1 Yttria-stabilised zirconia (YSZ) (Y,Yb)-Doped-Ba(Ce,Zr)O3−δ
Separator ZrO2 stabilised with PPS mesh Solid electrolyte (above) Solid electrolyte (above) Solid electrolyte (above) Solid electrolyte (above)
Electrode/catalyst (oxygen side) Nickel coated perforated stainless steel Iridium oxide High surface area nickel or NiFeCo alloys Perovskite-type (e.g., LSCF, LSM) Perovskite-type (e.g., LSCF, LSM
Electrode/catalyst (hydrogen side) Nickel coated perforated stainless steel Platinum nanoparticles on carbon black High surface area nickel Ni/YSZ Ni/YSZ, Ni-BZY/LSC, BCFYZ
Porous transport layer anode Nickel mesh (not always present) Platinum coated sintered porous titanium Nickel foam Coarse nickel-mesh or foam Coarse nickel-mesh or foam
Porous transport layer cathode Nickel mesh Sintered porous titanium or carbon cloth Nickel foam or carbon cloth None None
Bipolar plate anode Nickel-coated stainless steel Platinum-coated titanium Nickel-coated stainless steel None None
Bipolar plate cathode Nickel-coated stainless steel Gold-coated titanium Nickel-coated stainless steel Cobalt-coated stainless steel Cobalt-coated stainless steel
Frames and sealing PSU, PTFE, EPDM PTFE, PSU, ETFE PTFE, silicon Ceramic glass Ceramic glass