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. 2022 May 16;51(11):4583–4762. doi: 10.1039/d0cs01079k

Advantages and drawbacks of the monopolar and bipolar configurations of assembly for AWE cells.

Configuration Monopolar assembly Bipolar assembly
Advantages • Smaller electrolysis voltage due to the parallel stacking, resulting in larger electrical safety of operation • More homogeneous current feeding
• Absence of current leaks • Gain in voltage due to minored Ohmic drop in connectors/wires
• Impossibility of electrical shorts between anodes and cathodes • Smaller current intensity, resulting in less expensive electrical transformer/rectifier
Drawbacks • Less homogeneous current feeding • Larger installation voltage, inducing electrical safety issues
• Larger number of electrical contacts/wires • Possible current leaks between the inlets/outlets of electrolyte, feeding the cells in parallel (high potential differences applied to the same channel)
• Larger current intensity, resulting in more expensive electrical transformer/rectifier • Risk of contact failure between two neighbouring anodes/cathodes