Table 2. Key Odorants Identified in Post-Fermentation Products from Sour and Sweet Whey from the Bioreactor Culture.
concentration (μg/kg)d |
OAVf |
|||||||
---|---|---|---|---|---|---|---|---|
Compounda | Odorb | IR-DB 5c | IR-waxc | sour whey | sweet whey | OT in water (μg/kg)e | sour whey | sweet whey |
2,3-butanedione | buttery | 670 | 991 | 550 ± 11 | 610 ± 12 | 15 | 37 | 41 |
acetic acid | vinegar | 691 | 1445 | 250,120 ± 128 | 5126 ± 89 | 99,000 | 2.5 | <1 |
3-methylbutanal | malty | 695 | 948 | 45 ± 2 | 0.8 ± 0.05 | 0.5 | 90 | 1.6 |
3-methyl-1-butanol | fruity | 719 | 1204 | 121,511 ± 498 | 1546 ± 57 | 980 | 131 | 1.6 |
butanoic acid | cheesy | 836 | 1620 | 18,523 ± 212 | 17,450 ± 400 | 1000 | 18 | 17 |
3-(methylthio)-propanal | boiled potato | 908 | 1458 | 51 ± 0.8 | 48 ± 0.7 | 0.43 | 119 | 112 |
dimethyl trisulfide | cabbage | 985 | 1377 | 7 ± 0.05 | 6.8 ± 0.05 | 0.099 | 71 | 69 |
phenylacetaldehyde | honey | 1080 | 1644 | 12,040 ± 131 | 7105 ± 95 | 4 | 3010 | 1776 |
2-phenylethanol | rosy | 1124 | 1920 | 7090 ± 91 | 4125 ± 52 | 240 | 29 | 17 |
phenylacetic acid | honey | 1260 | 2568 | 1725 ± 32 | 3218 ± 38 | 1000 | 1.7 | 3.2 |
Compounds identified by comparison with reference compounds on the basis of the following criteria: retention index (RI), mass spectra obtained by MS (EI), and odor quality at the sniffing port.
Odor perceived at the sniffing port.
Retention indices on BD-5 and SUPELCOWAX 10 columns.
Mean of triplicates ± standard deviations.
OT: odor thresholds in water.44
OAV: odor activity values calculated by dividing the concentration of an analyte by its odor threshold value.