FIGURE 1.

CO₂ hydrogenation over various MOFs-based catalysts. (A) Interface bonding of sub-nanometer Cu clusters with Zr₆O₈ nodes over Cu/UiO-66 and its catalytic results in CO₂ hydrogenation to methanol. Reproduced with permission from Zhu et al. (2020). Copyright 2020 Springer Nature. (B) The Cu/ZnO_x NPs embedded UiO-bpy and its catalytic results in CO₂ hydrogenation to methanol. Reproduced with permission from An et al. (2017). Copyright 2017 American Chemical Society. (C) Structural evolution in the decomposition process of Ru/UiO-66 and its catalytic results obtained material for CO₂ hydrogenation to CH₄. Reproduced with permission from Lippi et al. (2017). Copyright 2017 Royal Society of Chemistry. (D) Fe/C-K catalyst fabricated through decomposition of Basolite F300 MOF and its catalytic results obtained material for CO₂ hydrogenation to CH₄. Reproduced with permission from Ramirez et al. (2018). Copyright 2018 American Chemical Society.