TABLE 1.
Summary performance of catalysts for CO2 hydrogenation reaction.
| Catalysts | Main Product | H2/CO2 Ratio | T (oC) | P (MPa) | Loading (Wt%) | XCO2 (%) | Selectivity (%) | STY (gkgcat −1 h−1) | TOS (h) | Ref |
|---|---|---|---|---|---|---|---|---|---|---|
| Cu-UiO-66 | Methanol | 3:1 | 175 | 1 | 1.0 | 1 | 100 | — | — | Rungtaweevoranit et al. (2016) |
| Cu/UiO-66 | Methanol | 3:1 | 250 | 3.2 | 1.4 | - | 29.6 | 679.76 | 50 | Zhu et al. (2020) |
| Cu@3D-ZrOx | Methanol | 3:1 | 260 | 4.5 | 12.4 | 13.1 | 78.8 | 796 | 105 | Liu et al. (2019) |
| Cu/ZnOx@UiO-66 | Methanol | 3:1 | 250 | 4 | 5.9 | 4.3 | 87 | 28.3 | 100 | Yang et al. (2021) |
| Cu/ZnOx@UiO-bpy | Methanol | 3:1 | 250 | 4 | 6.9 | 3.3 | 100 | 37.5 | 100 | An et al. (2017) |
| Cu-ZrO2(ZrO2@HKUST-1) | Methanol | 3:1 | 220 | 3 | 11 | 6.8 | 64.4 | 287.9 | 16 | Yu et al. (2021) |
| ZnO/Cu(Cu@ZIF-8) | Methanol | 3:1 | 260 | 4.5 | 57.6 | — | — | 933 | 76 | Hu et al. (2019) |
| PdZn (Cu@ZIF-8) | Methanol | 3:1 | 270 | 4.5 | — | 14 | 55 | 650 | 50 | Yin et al. (2018) |
| In2O3/Co3O4(In@ZIF-67) | Methanol | 3:1 | 300 | 5 | — | — | 87 | 650 | 100 | Pustovarenko et al. (2020) |
| Ni@MIL-101 | Methane | 8:1 | 320 | 0.1 | 10 | 56.4 | 91.6 | — | 10 | Mihet et al. (2019) |
| Ni@MOF-5 | Methane | 4:1 | 320 | 0.1 | 10 | 75.1 | 100 | — | 100 | Zhen et al. (2015) |
| Ni@UiO-66 | Methane | 3:1 | 300 | — | 20 | 57.6 | 100 | — | 100 | Zhao et al. (2018) |
| Ru/UiO-66 | Methane | 4:1 | 350 | 0.5 | 1.0 | 96 | 99 | — | — | Lippi et al. (2017) |
| K-CuZnAl + Na-Fe@C | Ethanol | 3:1 | 350 | 5 | — | 39.2 | 35 | — | 50 | Wang Y. et al., 2021 |
| Fe/C-K (Basolite F300) | Olefins | 3:1 | 320 | 3 | — | 40 | ∼40 | — | 50 | Ramirez et al. (2018) |