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. 2022 Aug 3;13:4506. doi: 10.1038/s41467-022-31909-w

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© The Author(s) 2022

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.

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Fig. 4 — a Splitting of the lowest energy peak for the YP device, on increasing B_Y, acquired at V_SD = –1.5 mV. A spin doublet is visible (gray lines), without exchange. b Dependence of the ground state and excited state transition potentials for DyP⁺/DyP on increasing B_z, acquired at V_SD = 1.5 mV. c Dependence of ground state and excited state transition potentials for DyP⁺/DyP on increasing B_x, acquired at V_SD = 1.5 mV. d Dependence of ground state and excited state transition potentials for DyP⁺/DyP on increasing B_y, acquired at V_SD = 1.5 mV. e Upper panel shows a separation of the magnetic levels vs. B_Y, for two DyP devices (triangles, full and open) and for the YP device (gray circles). Lines are fits to the data. Lower panel, expected evolution of the magnetic field levels for DyP⁺ (color) and YP⁺ (gray). Dy(III) spins are orange and porphyrin ones gray. All data were acquired at 20 mK.