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. Author manuscript; available in PMC: 2022 Aug 4.
Published in final edited form as: J Am Chem Soc. 2021 Oct 21;143(43):18346–18352. doi: 10.1021/jacs.1c10254

Figure 4.

Figure 4.

Proposed catalytic cycle for hydrogen peroxide formation through 1,2-diphenylhydrazine oxidation, accompanied by azoarene formation. The off-cycle formation of (EMindL)Cu(CH2Cl2) (4) is proposed to augment stability of the catalyst toward H2O2.