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. 2015 Jan 1;23(3):453–462. doi: 10.1016/j.jfda.2014.09.003

Table 1.

LC-MS/MS acquisition parameters for the target synthetic dyes.

Compound Precursor ion (m/z) Product ion (m/z) Declustering potential (V) Entrance potential (V) CEP (V) Collision energy (V) CXP (V)
Sudan Orange G 215.1 93.1 31 8 30 31 4
215.1 122.1 31 8 30 21 4
Dimethyl Yellow 226.1 120.1 41 8.5 30 43 4
226.1 105.1 41 8.5 30 25 4
Sudan I 249.1 93 26 4.5 30 33 4
249.1 156.1 26 4.5 30 21 4
Sudan II 277.1 121.1 26 4.5 30 25 4
277.1 106.1 26 4.5 30 55 4
Sudan Red G 279.1 123.1 26 4.5 30 23 4
279.1 108.1 26 4.5 30 47 4
Para Red 294.1 156.1 31 5 30 21 4
294.1 128.1 31 5 30 35 4
Sudan III 353.1 197.1 51 10.5 30 27 4
353.1 128.1 51 10.5 30 51 4
Sudan Red 7B 380.2 183.1 31 9 30 21 4
380.2 115.1 31 9 30 65 4
Sudan IV 381.1 224.1 51 9 30 31 4
381.1 225.1 51 9 30 25 4
381.1 143.1 51 9 30 37 4
381.1 104.1 51 9 30 83 4
Sudan Red B 381.2 224.1 56 10 30 29 4
381.2 225.1 56 10 30 29 4
381.2 156.1 56 10 30 27 4
381.2 134.1 56 10 30 27 4
Fast Garnet GBC 226.1 91 46 9.5 30 29 4
226.1 107 46 9.5 30 31 4
Fast Green FCF 381 80 −40 −10 −33 −98 −8
381 170 −40 −10 −33 −38 −8
Tartrazine 244 80 −21 −10 −29.5 −62 −8
244 198 −21 −10 −29.5 −20 −8
New Coccine 206 80 −35 −10 −28.4 −40 −8
268 206 −25 −10 −30 −18 −8
Indigo Carmine 226 198 −42 −10 −29 −27 −8
226 105 −42 −10 −29 −53 −8
Brilliant Blue 373 80 −45 −10 −33 −92 −8
373 170 −45 −10 −33 −42 −8
Sunset Yellow 203 171 −27 −10 −28 −20 −8
203 207 −27 −10 −28 −20 −8
Erythrosine 834 227 −22 −10 −45 −91 −8
834 127 −80 −10 −45 −84 −8
Allura Red 225 80 −32 −10 −29 −59 −8
225 136 −32 −10 −29 −34 −8
Amaranth 279 206 −32 −10 −30 −30 −8
279 221 −32 −10 −30 −22 −8

CEP = collision cell entrance potential; CXP = collision cell exit potential; LC-MS/MS = liquid chromatography/tandem mass spectrometry.