Table 1. Summary of the Rate Constants for Both First and Second Steps of the Reactions of the Ru–Pt Complexes with Nu at 35 °C^a.

		rate constants
complex	Nu	k21st × 101, M–1 s–1	k22nd × 102, M–1 s–1	k–12nd × 105, s–1
C1	Tu	1.45 ± 0.15	2.73 ± 0.10	1.04 ± 0.04
	l-Met	0.75 ± 0.11	0.37 ± 0.08a
	5′-GMP	0.34 ± 0.09	0.75 ± 0.04	0.20 ± 0.02
C2	Tu	4.26 ± 0.21	8.65 ± 0.15	4.35 ± 0.09
	l-Met	1.75 ± 0.18	1.02 ± 0.15a
	5′-GMP	0.96 ± 0.13	1.48 ± 0.08	0.84 ± 0.04
C3	Tu	7.57 ± 0.29	14.53 ± 0.22	10.99 ± 0.13
	l-Met	3.10 ± 0.26	2.08 ± 0.33a
	5′-GMP	1.39 ± 0.15	2.20 ± 0.10	2.22 ± 0.04

^ak₁^2nd × 10⁴, s^–1.