Table 2. EIS Variables for Mild Steel in 1 M HCl and with Varying Concentrations of DS1, DS2, DS3, and DS4 at 30 °C.
| inhibitors | conc. (mM) | Rs (Ω cm2) | Rct (Ω cm2) | n | Yo (μΩ sn cm–2) | Cdl (μF cm–2) | χ2 | –α (deg) | –S | % IEEIS |
|---|---|---|---|---|---|---|---|---|---|---|
| blank | 0 | 3.50 (±0.06) | 22.5 (±0.4) | 0.873 | 243.0 | 113.90 | 0.17431 | 41.54 | 0.64 | |
| DS1 | 0.10 | 2.18 (±0.02) | 114.0 (±0.2) | 0.869 | 213.0 | 121.61 | 0.43123 | 80.26 | ||
| 0.25 | 2.61 (±0.01) | 245.0 (±0.2) | 0.867 | 168.0 | 102.98 | 0.48832 | 90.81 | |||
| 0.50 | 2.15 (±0.02) | 265.0 (±0.3) | 0.844 | 148.0 | 81.34 | 0.50142 | 91.51 | |||
| 0.75 | 2.27 (±0.02) | 313.0 (±0.1) | 0.860 | 170.0 | 105.45 | 0.65431 | 92.81 | |||
| 1.00 | 3.18 (±0.03) | 736.0 (±0.1) | 0.852 | 120.0 | 78.72 | 0.60828 | 69.49 | 0.77 | 96.94 | |
| DS2 | 0.10 | 1.65 (±0.01) | 163.0 (±0.2) | 0.877 | 200.0 | 123.74 | 0.53373 | 86.20 | ||
| 0.25 | 2.51 (±0.03) | 409.0 (±0.1) | 0.864 | 69.9 | 39.95 | 0.42672 | 94.50 | |||
| 0.50 | 2.10 (±0.03) | 558.0 (±0.3) | 0.858 | 62.4 | 35.80 | 0.74196 | 95.97 | |||
| 0.75 | 2.44 (±0.02) | 688.0 (±0.3) | 0.838 | 68.1 | 37.69 | 0.63103 | 96.73 | |||
| 1.00 | 3.08 (±0.01) | 725.0 (±0.2) | 0.816 | 67.7 | 34.31 | 0.49849 | 66.42 | 0.69 | 96.90 | |
| DS3 | 0.10 | 2.60 (±0.02) | 81.0 (±0.4) | 0.865 | 220.0 | 117.34 | 0.35852 | 72.06 | ||
| 0.25 | 2.94 (±0.01) | 145.0 (±0.6) | 0.864 | 172.0 | 96.20 | 0.36617 | 84.48 | |||
| 0.50 | 2.55 (±0.02) | 149.0 (±0.2) | 0.870 | 180.0 | 104.82 | 0.36722 | 84.90 | |||
| 0.75 | 3.25 (±0.02) | 225.0 (±0.2) | 0.866 | 200.0 | 123.78 | 0.39842 | 90.00 | |||
| 1.00 | 3.95 (±0.02) | 395.0 (±0.3) | 0.856 | 175.0 | 111.64 | 0.41334 | 66.18 | 0.74 | 94.30 | |
| DS4 | 0.10 | 3.16 (±0.04) | 35.3 (±0.2) | 0.869 | 269.0 | 133.31 | 0.24624 | 36.26 | ||
| 0.25 | 4.22 (±0.04) | 47.2 (±0.3) | 0.873 | 210.0 | 107.33 | 0.24244 | 52.33 | |||
| 0.50 | 4.18 (±0.04) | 52.8 (±0.4) | 0.869 | 205.0 | 112.03 | 0.24399 | 57.39 | |||
| 0.75 | 3.78 (±0.02) | 88.6 (±0.3) | 0.873 | 173.0 | 94.21 | 0.23661 | 74.60 | |||
| 1.00 | 7.38 (±0.01) | 90.6 (±0.4) | 0.868 | 144.0 | 74.44 | 0.14991 | 49.54 | 0.58 | 75.17 |