Table 2.
EIS parameters of MS in the presence of different concentrations of DPH in 1 M HCl solution.
Concentration (ppm) | Immersion time (h) | Rs (Ω cm2) | Rct (Ω cm2) | CPE | Cdl (µF cm−2) | η (%) | τ (s) | θEIS | |
---|---|---|---|---|---|---|---|---|---|
Y0 (µsn Ω−1 cm−2) | n | ||||||||
Blank | 1 | 1.71 ± 0.01 | 46.75 ± 0.17 | 92.25 ± 1.82 | 0.9 ± 0.01 | 34.73 | – | 0.00162 | – |
3 | 1.65 ± 0.01 | 72.84 ± 0.24 | 104.86 ± 1.34 | 0.89 ± 0.01 | 35.85 | – | 0.00261 | – | |
6 | 1.65 ± 0.01 | 77.88 ± 0.3 | 117.59 ± 1.78 | 0.89 ± 0.01 | 40.78 | – | 0.00317 | – | |
24 | 1.49 ± 0.01 | 60.04 ± 0.42 | 175.2 ± 4.12 | 0.9 ± 0.01 | 69.86 | – | 0.00419 | – | |
250 | 1 | 1.51 ± 0.07 | 271.1 ± 4.21 | 63.6 ± 2.96 | 0.86 ± 0.01 | 14.09 | 82.75 | 0.00382 | 59 |
3 | 1.59 ± 0.09 | 404.4 ± 6.32 | 46.3 ± 2.16 | 0.88 ± 0.01 | 12.64 | 81.99 | 0.00511 | 64 | |
6 | 1.72 ± 0.11 | 413.8 ± 9.25 | 44.5 ± 2.72 | 0.89 ± 0.01 | 13.78 | 81.17 | 0.00570 | 66 | |
24 | 1.19 ± 0.09 | 338.3 ± 5.98 | 49.2 ± 2.67 | 0.89 ± 0.01 | 14.78 | 82.25 | 0.005 | 78 | |
500 | 1 | 1.74 ± 0.2 | 592.6 ± 12.04 | 92.86 ± 4.44 | 0.78 ± 0.01 | 7.91 | 92.11 | 0.00468 | 77 |
3 | 2.3 ± 0.18 | 685.1 ± 9.19 | 65.96 ± 2.54 | 0.81 ± 0.01 | 8.38 | 89.37 | 0.0057 | 76 | |
6 | 2.25 ± 0.19 | 867.2 ± 12.77 | 53.55 ± 2.27 | 0.84 ± 0.01 | 9.55 | 91.02 | 0.0082 | 76 | |
24 | 1.93 ± 0.05 | 478.2 ± 4.26 | 53.74 ± 1.26 | 0.88 ± 0.01 | 15.37 | 87.44 | 0.00735 | 77 | |
750 | 1 | 3.08 ± 0.22 | 628 ± 12.72 | 111.19 ± 7.70 | 0.78 ± 0.01 | 11.70 | 92.55 | 0.00734 | 66 |
3 | 2.68 ± 0.19 | 751.3 ± 13.75 | 85.97 ± 3.60 | 0.8 ± 0.01 | 10.58 | 90.30 | 0.0079 | 70 | |
6 | 2.4 ± 0.20 | 877.5 ± 14.68 | 73.5 ± 3.21 | 0.82 ± 0.01 | 11.02 | 91.12 | 0.00966 | 72 | |
24 | 4.03 ± 0.24 | 670.8 ± 9.6 | 73.19 ± 3.18 | 0.84 ± 0.01 | 15.54 | 91.05 | 0.01042 | 70 | |
1000 | 1 | 4.52 ± 0.26 | 748.2 ± 16.36 | 89.78 ± 4.55 | 0.8 ± 0.01 | 12.72 | 93.75 | 0.0095 | 63 |
3 | 4.66 ± 0.24 | 846.9 ± 0.24 | 77.37 ± 3.3 | 0.81 ± 0.01 | 12.03 | 91.40 | 0.01019 | 66 | |
6 | 4.18 ± 0.24 | 909.1 ± 13.35 | 64.95 ± 3.30 | 0.83 ± 0.01 | 12.07 | 91.43 | 0.01097 | 70 | |
24 | 2.99 ± 0.09 | 977.5 ± 9.70 | 82.82 ± 1.94 | 0.79 ± 0.01 | 9.10 | 93.86 | 0.00889 | 86 |