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. 2022 Aug 4;12:13450. doi: 10.1038/s41598-022-17589-y

Table 2.

EIS parameters of MS in the presence of different concentrations of DPH in 1 M HCl solution.

Concentration (ppm) Immersion time (h) Rs (Ω cm2) Rct (Ω cm2) CPE Cdl (µF cm−2) η (%) τ (s) θEIS
Y0 (µsn Ω−1 cm−2) n
Blank 1 1.71 ± 0.01 46.75 ± 0.17 92.25 ± 1.82 0.9 ± 0.01 34.73 0.00162
3 1.65 ± 0.01 72.84 ± 0.24 104.86 ± 1.34 0.89 ± 0.01 35.85 0.00261
6 1.65 ± 0.01 77.88 ± 0.3 117.59 ± 1.78 0.89 ± 0.01 40.78 0.00317
24 1.49 ± 0.01 60.04 ± 0.42 175.2 ± 4.12 0.9 ± 0.01 69.86 0.00419
250 1 1.51 ± 0.07 271.1 ± 4.21 63.6 ± 2.96 0.86 ± 0.01 14.09 82.75 0.00382 59
3 1.59 ± 0.09 404.4 ± 6.32 46.3 ± 2.16 0.88 ± 0.01 12.64 81.99 0.00511 64
6 1.72 ± 0.11 413.8 ± 9.25 44.5 ± 2.72 0.89 ± 0.01 13.78 81.17 0.00570 66
24 1.19 ± 0.09 338.3 ± 5.98 49.2 ± 2.67 0.89 ± 0.01 14.78 82.25 0.005 78
500 1 1.74 ± 0.2 592.6 ± 12.04 92.86 ± 4.44 0.78 ± 0.01 7.91 92.11 0.00468 77
3 2.3 ± 0.18 685.1 ± 9.19 65.96 ± 2.54 0.81 ± 0.01 8.38 89.37 0.0057 76
6 2.25 ± 0.19 867.2 ± 12.77 53.55 ± 2.27 0.84 ± 0.01 9.55 91.02 0.0082 76
24 1.93 ± 0.05 478.2 ± 4.26 53.74 ± 1.26 0.88 ± 0.01 15.37 87.44 0.00735 77
750 1 3.08 ± 0.22 628 ± 12.72 111.19 ± 7.70 0.78 ± 0.01 11.70 92.55 0.00734 66
3 2.68 ± 0.19 751.3 ± 13.75 85.97 ± 3.60 0.8 ± 0.01 10.58 90.30 0.0079 70
6 2.4 ± 0.20 877.5 ± 14.68 73.5 ± 3.21 0.82 ± 0.01 11.02 91.12 0.00966 72
24 4.03 ± 0.24 670.8 ± 9.6 73.19 ± 3.18 0.84 ± 0.01 15.54 91.05 0.01042 70
1000 1 4.52 ± 0.26 748.2 ± 16.36 89.78 ± 4.55 0.8 ± 0.01 12.72 93.75 0.0095 63
3 4.66 ± 0.24 846.9 ± 0.24 77.37 ± 3.3 0.81 ± 0.01 12.03 91.40 0.01019 66
6 4.18 ± 0.24 909.1 ± 13.35 64.95 ± 3.30 0.83 ± 0.01 12.07 91.43 0.01097 70
24 2.99 ± 0.09 977.5 ± 9.70 82.82 ± 1.94 0.79 ± 0.01 9.10 93.86 0.00889 86