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. Author manuscript; available in PMC: 2022 Aug 5.
Published in final edited form as: ACS ES T Eng. 2022 Apr 11;2(5):780–793. doi: 10.1021/acsestengg.1c00367

Table 1.

Summarized Hourly Pollutant Concentrations and Calibration Model Performance during the Training and Evaluation Periodsa

Training Period Statistics Evaluation Period Statistics
Average ± Standard Deviation Median (5th-95th) RMSE r Average ± Standard Deviation Median (5th-95th) RMSE (% bias) r
PM2.5 (μg/m3)
Reference 8.0 ± 6.0 7.0 (1.0–18.0) 8.8 ± 6.0 7.0 (1.0–19.0)
Uncalibrated Sensor 12.7 ± 12.3 8.8 (1.0–37.5) 9.2 0.84 12.4 ± 11.7 9.2 (1.0–37.4) 8.6 (43%) 0.80
Calibrated Sensor 8.0 ± 5.4 6.6 (2.4–17.9) 2.8 0.89 8.0 ± 5.0 6.9 (2.5–18.3) 3.4 (−10%) 0.85
CO (ppb)
Reference 234 ± 144 197 (137–446) 282 ± 248 203 (134–688)
Uncalibrated Sensor 0.51 0.84
Calibrated Sensor 234 ± 128 199 (151–417) 60.5 0.90 297 ± 238 218 (164–688) 58.9 (5.6%) 0.97
NO2 (ppb)
Reference 7.9 ± 7.9 5.0 (1.0–26.0) 8.1 ± 7.0 5.0 (1.0–23.0)
Uncalibrated Sensor 0.71 0.68
Calibrated Sensor using Reference Data for Pollutant Predictors 8.1 ± 7.3 5.9 (2.1–23.7) 3.3 0.91 7.8 ± 5.7 5.9 (1.8–19.1) 3.5 (−9.0%) 0.88
Calibrated Sensor using Sensor Data for Pollutant Predictors 7.9 ± 7.1 5.9 (0.5–23.5) 3.6 0.90 9.4 ± 5.8 7.6 (0.5–20.4) 3.6 (12%) 0.88
O3 (ppb)
Reference 35.5 ± 15.7 36.0 (7.0–60.0) 28.5 ± 14.9 28.0 (4.0–56.0)
Uncalibrated Sensor 0.52 0.52
Calibrated Sensor using Reference Data for Pollutant Predictors 35.8 ± 13.7 36.5 (10.5–58.1) 6.9 0.90 28.4 ± 13.6 29.8 (7.0–55.8) 7.4 (−7.1%) 0.86
Calibrated Sensor using Sensor Data for Pollutant Predictors 35.6 ± 13.6 36.1 (9.4–57.6) 7.1 0.90 28.3 ± 15.5 26.6 (3.6–55.5) 7.0 (−4.0%) 0.89
NO (ppb)
Reference 3.0 ± 11.0 0.5 (0.1–11.2) 3.3 ± 10.0 0.6 (0.1–16.5)
Uncalibrated Sensor 0.81 0.77
Calibrated Sensor using Reference Data for Pollutant Predictors 3.0 ± 10.3 0.6 (0.01–12.3) 3.0 0.96 2.8 ± 8.3 0.5 (0.01–13.7) 3.3 (−15%) 0.96
Calibrated Sensor using Sensor Data for Pollutant Predictors 3.0 ± 10.0 0.6 (0.01–12.9) 3.4 0.95 3.3 ± 7.8 0.8 (0.01–13.9) 3.2 (−2.7%) 0.97
Temperature (°C)
Ambient Reference 15.1 ± 9.7 16.6 (−0.5 to 29.4) 13.0 ± 10.2 11.6 (−1.6 to 28.8)
Internal Sensor 20.8 ± 10.9 21.8 (3.4–38.4) 19.2 ± 10.6 18.0 (3.1–37.4)
RH (%)
Ambient Reference 61.8 ± 19.9 61 (29–91) 65.4 ± 17.6 66 (38–91)
Internal Sensor 49.8 ± 16.0 49.4 (24.2–73.6) 52.4 ± 13.8 53.4 (30.4–73.0)
a

In the case of NO2, O3, and NO, only periods when the predictors for both models were available were included in the summary values, which allows for direct comparison.