. 2022 Jul 21;13(30):6889–6895. doi: 10.1021/acs.jpclett.2c01768

Table 1. Peak Maxima (eKE) of I_meas(E) and I_true(E), Full Widths at Half-Maxima (FWHMs) of eKE_true, and One- and Two-Photon Binding Energies, hν – eKE and 2hν – eKE, Obtained from the Photoelectron Spectra of Water, Phenol, and Phenolate Presented in Figures 2 and 3 ^a.

molecule	λ/nm	eKE_meas/eV	eKE_true/eV	FWHM_true/eV	hν – eKE/eV	2hν – eKE/eV
water	200.2	0.83 ± 0.07	1.03 ± 0.07	1.27	5.16 ± 0.07	11.36 ± 0.09
phenol	290.0	0.67 ± 0.07	0.79 ± 0.07	0.94		7.76 ± 0.09
	278.6	0.70 ± 0.07	0.73 ± 0.07	0.90	3.72 ± 0.07	8.17 ± 0.09
	272.5	0.73 ± 0.07	0.77 ± 0.07	0.92	3.78 ± 0.07	8.33 ± 0.09
	266.6	0.76 ± 0.07	0.81 ± 0.07	0.96	3.84 ± 0.07	8.49 ± 0.09
phenolate	320.0	0.62 ± 0.07	0.73 ± 0.07	0.87		7.02 ± 0.09
	298.7	0.92 ± 0.07	0.98 ± 0.07	0.98	3.14 ± 0.07	7.32 ± 0.09
	291.7	0.95 ± 0.07	1.01 ± 0.07	1.04	3.21 ± 0.07	7.49 ± 0.09
	285.0	1.00 ± 0.07	1.06 ± 0.07	1.09	3.29 ± 0.07	7.64 ± 0.09

Vertical ionization and detachment energies arising from non-resonant excitation are in bold.

Table 1. Peak Maxima (eKE) of Imeas(E) and Itrue(E), Full Widths at Half-Maxima (FWHMs) of eKEtrue, and One- and Two-Photon Binding Energies, hν – eKE and 2hν – eKE, Obtained from the Photoelectron Spectra of Water, Phenol, and Phenolate Presented in Figures 2 and 3a.