. 2022 Jul 29;38(31):9697–9707. doi: 10.1021/acs.langmuir.2c01391

Table 1. LB Experiments for RuC_n(PF₆)₂: Monolayer Properties at the Collapse (Average Values) and Parameter Fits for the Modified Volmer Model (Data of Figure 3).

	monolayer properties at the collapse			parameter fits for the modified Volmer model
n (chain length)	surface pressure Π_col (mN/m)	surface tension γ_col^a (mN/m)	area per molecule A_col (Å²)	α₀ (Å²)	ε (m/N)	Π* (mN/m)	standard error of the estimate (Å²)
9				97	6.7	9.0	0.55
12	34.1 ± 0.4	38.2 ± 0.4	104 ± 1	140	8.3	6.1	1.35
15	41.3 ± 0.5	31.0 ± 0.5	98 ± 4	180	12	5.2	0.71
17	45 ± 1	27.3 ± 1	118 ± 2	160	6.3	6.2	1.27

γ = γ₀ – Π with γ₀ = 72.3 mN/m

Table 1. LB Experiments for RuCn(PF6)2: Monolayer Properties at the Collapse (Average Values) and Parameter Fits for the Modified Volmer Model (Data of Figure 3).