Table 3. List of the Surface-Related Parameters of All RuCn(Cl)2 Compounds.
| Rosen parameters |
parameter fits for Volmer model |
|||||||
|---|---|---|---|---|---|---|---|---|
| n | molecular mass from elemental analysis (g/mol) | CMC (μmol/L) | γmin (mN/m) | C20 (μmol/L) | 1/K (μmol/L) | α (Å2) | area/molecule at the CMC (Å2) | standard error of the estimate |
| 9 | 961.09 | 41 | 29 | 5.0 | 2.3 | 19 | 28 | 0.14 |
| 12 | 977.18 | 320 | 43 | 31 | 0.010 | 120 | 230 | 0.74 |
| 15 | 1079.36 | 2.9 | 44 | 0.93 | 0.23 | 27 | 51 | 0.29 |
| 17 | 1117.45 | n.d.a | n.d. | n.d.a | n.d.a | 22b | n.d.a | n.d.a |
n.d.: not determined.
This value has been deduced from the interfacial viscoelasticity data (see Figure S4 and the Supporting Information).