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. 2022 Jul 27;61(31):12415–12424. doi: 10.1021/acs.inorgchem.2c01868

Table 4. Reaction Time for the Oxidation of [MO(PyS)2(PMe3)2] with 1000 equiv of DMSO to [MO2(PyS)2]a.

compound reaction completed after (h)
[MoO(PyS)2(PMe3)2] 9
[WO(PyS)2(PMe3)2] (3) 5
a

Conditions: to a 3 mL of CH2Cl2 solution of the [MO(PMe3)2(PyS)2] (0.3 μmol) in a quartz cuvette, 1000 equiv of DMSO was added in the glove box. UV–vis measurement started 3 min after the preparation of the sample. The screening was performed at 25 °C.