Table 2.
UV/Vis Spectrophotometric Method | ||||
---|---|---|---|---|
A = n + kC | n | Error n (Sn) | k(slope) (Mol−1 dm3) |
Error k (Sk) (Mol−1 dm3) |
A = 1.000 + 9000 × C | 1.000 | 0.005 | 9000 | 100 |
LOD = 3.3 × Sn/k | LOQ = 10 × Sn/k | |||
1.8 × 10−6 mol dm−3 | 5.7 × 10−6 mol dm−3 | |||
Briggs–Rauscher oscillatory method | ||||
τinh = n + kC | n(s) | error n (Sn) (s) |
k(slope) (mol−1 dm3 s) |
error k (Sk) (mol−1 dm3 s) |
τinh = 3 + 4 × 108 × Cind | 3 | 2 | 4 × 108 | 1 × 107 |
LOD = 3.3 × Sn/k | LOQ = 10 × Sn/k | |||
1.65 × 10−8 mol dm−3 | 5 × 10−8 mol dm−3 |