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. 2022 Aug 3;27(15):4950. doi: 10.3390/molecules27154950

Table 2.

1H (400 MHz) and 13C (100 MHz) NMR data of (1) in CDCl3.

Position δH (J in Hz) δC (Type) COSY HMBC
2 / 161.2, C
3 6.11, d (9.4) 112.8, CH H-4 C-9
4 7.53, d (9.4) 143.7, CH H-3 C-2, C-10
5 7.29, d (8.6) 127.1, CH H-6 C-4, C-7, C-9, C-10
6 6.79, d (8.6) 107.2, CH H-5 C-7, C-8
7 / 160.8, C
8 / 114.7, C
9 / 153.5, C
10 / 110.3, C
11a 3.41, dd (13.6, 10.8) 23.3, CH2 H-12 C-7, C-8, C-10
11b 3.13, dd (13.6, 2.4)
12 5.23, dd (10.6, 2.5) 78.7, CH H-11 C-8, C-11, C-14, C-15, C-9′
13 72.7, C
14 1.41, s 25.3, CH3 C-12, C-15
15 1.35, s 26.6, CH3 C-12, C-14
1′ / 116.0, C
2′ / 156.8, C
3′ / 110.3, C
4′ / 160.0, C
5′ 6.38, d (8.7) 102.4, CH H-6′ C-1′, C-3′
6′ 7.31, d (8.7) 130.0, CH H-5′ C-2′, C-4′, C-7′
7′ 7.70, d (16.1) 140.1, CH H-8′ C-2′, C-6′, C-9′
8′ 6.28, d (16.1) 115.8, CH H-7′ C-1′
9′ / 167.2, C
10′ 4.94, d (7.4) 79.3, CH C-2′, C-3′, C-4’, C-11′, C-12′, C-15′
11′ 4.27, d (7.4) 77.1, CH C-10′, C-12′, C-13′, C-14′
12′ / 142.9, C
13′a 4.75, s 113.6, CH2 C-11′, C-12′, C-14′
13′b 4.62, s C-11′, C-12′, C-14′
14′ 1.75, s 17.9, CH3 C-11′, C-13′
15′a 3.68, dq (14.0, 7.0) 66.5, CH2 H-16′ C-10′, C-16′
15′b 3.59, dq (14.0, 7.0)
16′ 1.27, t (7.0) 15.0, CH3 H-15′ C-15′
7-OCH3 3.92, s 56.2, CH3 C-7
4′-OCH3 3.75, s 55.4, CH3 C-4′
2′-OH 8.98, s C-2′