Table 2.
Position | δH (J in Hz) | δC (Type) | COSY | HMBC |
---|---|---|---|---|
2 | / | 161.2, C | ||
3 | 6.11, d (9.4) | 112.8, CH | H-4 | C-9 |
4 | 7.53, d (9.4) | 143.7, CH | H-3 | C-2, C-10 |
5 | 7.29, d (8.6) | 127.1, CH | H-6 | C-4, C-7, C-9, C-10 |
6 | 6.79, d (8.6) | 107.2, CH | H-5 | C-7, C-8 |
7 | / | 160.8, C | ||
8 | / | 114.7, C | ||
9 | / | 153.5, C | ||
10 | / | 110.3, C | ||
11a | 3.41, dd (13.6, 10.8) | 23.3, CH2 | H-12 | C-7, C-8, C-10 |
11b | 3.13, dd (13.6, 2.4) | |||
12 | 5.23, dd (10.6, 2.5) | 78.7, CH | H-11 | C-8, C-11, C-14, C-15, C-9′ |
13 | 72.7, C | |||
14 | 1.41, s | 25.3, CH3 | C-12, C-15 | |
15 | 1.35, s | 26.6, CH3 | C-12, C-14 | |
1′ | / | 116.0, C | ||
2′ | / | 156.8, C | ||
3′ | / | 110.3, C | ||
4′ | / | 160.0, C | ||
5′ | 6.38, d (8.7) | 102.4, CH | H-6′ | C-1′, C-3′ |
6′ | 7.31, d (8.7) | 130.0, CH | H-5′ | C-2′, C-4′, C-7′ |
7′ | 7.70, d (16.1) | 140.1, CH | H-8′ | C-2′, C-6′, C-9′ |
8′ | 6.28, d (16.1) | 115.8, CH | H-7′ | C-1′ |
9′ | / | 167.2, C | ||
10′ | 4.94, d (7.4) | 79.3, CH | C-2′, C-3′, C-4’, C-11′, C-12′, C-15′ | |
11′ | 4.27, d (7.4) | 77.1, CH | C-10′, C-12′, C-13′, C-14′ | |
12′ | / | 142.9, C | ||
13′a | 4.75, s | 113.6, CH2 | C-11′, C-12′, C-14′ | |
13′b | 4.62, s | C-11′, C-12′, C-14′ | ||
14′ | 1.75, s | 17.9, CH3 | C-11′, C-13′ | |
15′a | 3.68, dq (14.0, 7.0) | 66.5, CH2 | H-16′ | C-10′, C-16′ |
15′b | 3.59, dq (14.0, 7.0) | |||
16′ | 1.27, t (7.0) | 15.0, CH3 | H-15′ | C-15′ |
7-OCH3 | 3.92, s | 56.2, CH3 | C-7 | |
4′-OCH3 | 3.75, s | 55.4, CH3 | C-4′ | |
2′-OH | 8.98, s | C-2′ |