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. Author manuscript; available in PMC: 2022 Aug 13.
Published in final edited form as: J Am Chem Soc. 2021 Jan 4;143(2):817–829. doi: 10.1021/jacs.0c09839

Figure 5.

Figure 5.

(a) Initial rate for conversion of 7 into 8 over the first 10% as a function of catalyst loadings while holding initial azide 7 concentration constant. Every measurement is done in triplicate, and error bars represent standard deviations; (b) Initial rate for conversion of 7 into 8 over the first 10% as a function of initial azide 7 concentration while holding catalyst concentration constant. Every measurement is done in triplicate, and error bars represent standard deviations; (c) Plotting the first 10% conversion of 9H2 (blue) and 9D2 (red) into 10H and 10D over time, respectively. Intermolecular KIE is derived by taking the ratio of the slopes of the linear fits [KIE = 1.35 ± 0.03 (60 °C)]. Every measurement is done in triplicate, and error bars represent standard deviations.