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. 2022 Jul 28;144(31):14012–14015. doi: 10.1021/jacs.2c04935

Table 1. Lifetimes for Kinetic Processes Following Photo-oxidation of Aqueous Phenolate in the Bulk and at the Water/Air Interface.

  kp–1/ps kn–1/ps kd–1/ps kb–1/ps
Bulk 0.5 ± 0.1 32 ± 2 43 ± 4
Surface ≪0.2a 16 ± 1 11 ± 2 78 ± 6
a

Lifetime was actually not included in the fit, but is taken to be (kpkd and kn).