Table 1. Lifetimes for Kinetic Processes Following Photo-oxidation of Aqueous Phenolate in the Bulk and at the Water/Air Interface.
| kp–1/ps | kn–1/ps | kd–1/ps | kb–1/ps | |
|---|---|---|---|---|
| Bulk | 0.5 ± 0.1 | 32 ± 2 | 43 ± 4 | – |
| Surface | ≪0.2a | 16 ± 1 | 11 ± 2 | 78 ± 6 |
Lifetime was actually not included in the fit, but is taken to be (kp ≫ kd and kn).