Table 1. Absorption Maxima (λabsmax), Extinction Coefficients (ε), Emission Maxima (λemmax), Fluorescence Quantum Yields (Φfl), Fluorescence Lifetimes (τfl), Isomerization Quantum Yields (Φisom), Conversion Degree at Photostationary State upon 365 nm Irradiation (α365nm = [CF]/C0) and upon 470 nm Irradiation (α470nm = [OF]/C0), and Photofatigue Resistance (N1/2) of Diarylethenes DAE and DAE-COOH and Their Complexes with CB7 (DAE@CB7 and DAE-COOH@CB7) Measured in Aqueous Solutions. (OF: Open Form, CF: Closed Form).
λabsmax (nm)/ε × 10–3 (M–1 cm–1) |
λemmax (nm) | Φfl | τfl (ns) | Φisom |
||||||
---|---|---|---|---|---|---|---|---|---|---|
OF | CF | CF | CF | CF | OF → CF | CF → OF | α365nm | α470nm | N1/2 | |
DAE | 291/15.6, 333/13.6 | 444/27.9 | 519, 548 | 0.40 | 1.83 | 0.34 | 6.4 × 10–3 | 1.00 | 1.00 | 80 |
DAE@CB7 | 449/29.3 | 519, 548 | 0.63 | 2.33 | 0.35 | 6.9 × 10–3 | 2560 | |||
DAE-COOH | 294/18.7, 327/15.8 | 446/31.6 | 519, 550 | 0.41 | 1.80 | 0.29 | 9.1 × 10–3 | 1.00 | 1.00 | 19 |
DAE-COOH@CB7 | 450/33.9 | 520, 553 | 0.62 | 2.30 | 0.35 | 9.2 × 10–3 | 286 |