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. 2022 Jun 29;61(27):10533–10547. doi: 10.1021/acs.inorgchem.2c01438

Table 2. Electrochemical Potentials of [Mn(CNdippPhOMe2)6]PF6 in Comparison with Similar Compounds from the Literature.

compound E1/2 (MnI/II) vs SCE (V) E1/2 (MnII/III) vs SCE (V)
[Mn(CNdippPhOMe2)6]PF6a 1.21 1.74b
[Mn(Ltri)2]PF653  a,c 1.00  
[Mn(Lbi)3]PF653 a,d 1.05  
[Mn(CNPh)6]PF645 e 1.01 1.91
[Mn(CNMe)6]PF645 e 0.47 1.59
a

In (dry and deaerated) CH2Cl2 at 20 °C with TBAPF6 (0.1 M) as the supporting electrolyte.

b

Only observable during one cycle (irreversible).

c

Ltri = 5,5′-(2-isocyano-5-methyl-1,3-phenylene)bis(2-(3,5-di-tert-butyl-2-isocyanophenyl)thiophene).

d

Lbi = 2,5-bis(3,5-di-tert-butyl-2-isocyanophenyl)thiophene.

e

In CH2Cl2 (5 × 10–3 M) with TBAClO4 (0.1 M) as the supporting electrolyte.