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. 2022 Jul 25;24(32):19287–19301. doi: 10.1039/d2cp02240k

Experimental sources, denoted with unique tags, used to construct the spectroscopic network of the hyperfine-unresolved rovibronic transitions of 12CH. Given are the wavenumber range (Range), in cm−1, of each source, the number actual (A) and validated (V) transitions, plus uncertainty (unc.) statistics, in cm−1, with Avg. = average and Max. = maximum.

Taga Range A/V Avg. unc. Max. unc.
13TrHeHiTa102 0.02–0.11 2/2 2.96 × 10−9 4.92 × 10−9
06McMoBrTh99 0.11–0.49 3/3 7.04 × 10−7 1.00 × 10−6
85StWoBr79 0.11–0.11 1/1 1.69 × 10−4 1.69 × 10−4
83BrBr74 0.16–0.81 4/4 2.01 × 10−4 5.98 × 10−4
84BrBr76 0.24–23529.83 82/81 5.59 × 10−3 2.80 × 10−2
83BoDeDe73 1.46–2.54 5/5 9.34 × 10−6 1.33 × 10−5
95Zachwiej_C91 14.27–15781.09 138/138 5.58 × 10−3 1.58 × 10−2
00Amano96 17.77–17.91 2/2 8.56 × 10−5 1.50 × 10−4
13TrHeToLe20 17.77–17.91 2/1 3.50 × 10−7 3.50 × 10−7
01DaEvBr97 67.07–141.78 8/8 5.78 × 10−5 1.33 × 10−4
10CoBe101 2093.93–3036.75 205/204 2.04 × 10−2 5.26 × 10−2
91BeBrOlHa89 2162.60–27561.99 572/570 9.84 × 10−3 7.36 × 10−2
87Bernath83 2309.84–2953.36 183/183 5.52 × 10−3 1.46 × 10−2
89MeGrSaFa10 2332.12–3037.34 378/378 5.38 × 10−3 3.50 × 10−2
84LuAm77 2580.65–2937.06 54/54 1.15 × 10−3 3.28 × 10−3
96KePaRyZa92 20202.55–27562.00 231/228 1.73 × 10−2 1.33 × 10−1
95Zachwiej91 20232.36–24007.21 1015/974 1.36 × 10−2 2.80 × 10−1
14MaPlVaCo9 21842.11–31628.30 679/535 5.11 × 10−1 2.04
41Gero63 22372.25–27561.60 1108/1091 1.29 × 10−1 1.59
90BeKePaRy87 23037.98–23878.85 557/498 6.14 × 10−2 4.58 × 10−1
98KuHsHuLe94 24475.90–27548.20 111/93 2.23 × 10−1 5.78 × 10−1
91Para90 25348.38–25823.34 59/50 8.45 × 10−3 2.28 × 10−2
99LiKuHsLe95 30980.42–32048.74 124/116 2.00 × 10−1 2.00 × 10−1
19MeLiUb105 31002.32–32269.09 213/212 6.85 × 10−2 5.00 × 10−1
32Heimer62 31049.00–32388.47 159/133 2.00 × 10−1 2.00 × 10−1
69HeJo66 31226.14–64621.60 150/115 3.78 × 10−1 4.14
97BeKeRy93 31387.80–32202.22 63/50 3.55 × 10−2 8.50 × 10−2
86UbMeTeDy81 31677.57–31908.06 35/32 3.17 × 10−3 8.25 × 10−3
85ChChCo78 63685.00–64155.00 48/46 4.568 8.87
87ChPaChCo84 63686.10–69110.30 157/149 2.04 7.99
a

Tags denote experimental data-source segments employed during this study. The column ‘Range’ indicates the range (in cm−1) corresponding to validated wavenumber entries within the experimental transitions list. ‘A/V’ is an ordered pair, where A and V are the number of assigned and validated transitions related to a given source segment, respectively, obtained at the end of the Marvel analysis.