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. 2022 Aug 17;13:4850. doi: 10.1038/s41467-022-32563-y

Table 4.

n-Hexadecane deconstruction with the additional Zeo-Y_H-based catalysts with varying SARs

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Entry Catalyst Conv. (%) C1-4 Yield (%)* C5-16 Yield (%)*
1 Zeo-Y_H 26.7 ± 1.4 3.3 23.3
2 Zeo-Y_H [60] 24.6 ± 1.2 3.8 20.8
3 Zeo-Y_H [80] 14.9 ± 0.6 2.0 12.8
4 Ni/Zeo-Y_H 20.9 ± 1.3 0.4 20.5
5 Ni/Zeo-Y_H [60] 5.8 ± 0.5 0.9 4.9
6 Ni/Zeo-Y_H [80] 4.9 ± 0.7 0.6 4.3
7 Ru/Zeo-Y_H 99.0 ± 1.0 92.4 6.9
8 Ru/Zeo-Y_H [60] 99.0 ± 1.0 98.0 2.0
9 Ru/Zeo-Y_H [80] 99.0 ± 1.0 97.2 2.8

Reaction conditions: n-hexadecane (1.59 g, 7.0 mmol), catalyst (0.1 g, metal loading = 2.5 wt%), S/C ratio (substrate/catalyst weight ratio) ~16, 45 bar H2, 375 °C, 2 h.

*All yields were calculated as the carbon yield and isomerized C16 (isoC16) are considered as products.