Table 4.
n-Hexadecane deconstruction with the additional Zeo-Y_H-based catalysts with varying SARs
| Entry | Catalyst | Conv. (%) | C1-4 Yield (%)* | C5-16 Yield (%)* |
|---|---|---|---|---|
| 1 | Zeo-Y_H | 26.7 ± 1.4 | 3.3 | 23.3 |
| 2 | Zeo-Y_H [60] | 24.6 ± 1.2 | 3.8 | 20.8 |
| 3 | Zeo-Y_H [80] | 14.9 ± 0.6 | 2.0 | 12.8 |
| 4 | Ni/Zeo-Y_H | 20.9 ± 1.3 | 0.4 | 20.5 |
| 5 | Ni/Zeo-Y_H [60] | 5.8 ± 0.5 | 0.9 | 4.9 |
| 6 | Ni/Zeo-Y_H [80] | 4.9 ± 0.7 | 0.6 | 4.3 |
| 7 | Ru/Zeo-Y_H | 99.0 ± 1.0 | 92.4 | 6.9 |
| 8 | Ru/Zeo-Y_H [60] | 99.0 ± 1.0 | 98.0 | 2.0 |
| 9 | Ru/Zeo-Y_H [80] | 99.0 ± 1.0 | 97.2 | 2.8 |
Reaction conditions: n-hexadecane (1.59 g, 7.0 mmol), catalyst (0.1 g, metal loading = 2.5 wt%), S/C ratio (substrate/catalyst weight ratio) ~16, 45 bar H2, 375 °C, 2 h.
*All yields were calculated as the carbon yield and isomerized C16 (isoC16) are considered as products.