Table 5. Acidity Determination of the Catalysts Using n-Butyl Amine Titration.
acid
strength of the catalysts (mmol/g) |
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entry | Hammett indicator | color of the indicator after addition in the catalyst test solution | FS-1 | FP-1 | FC-1 | SiO2 + Al2O3 + Fe2O3 60% + 35% + 5% |
1 | methyl red (pKa = +4.8) red in acid forms yellow in the base form | red to all catalysts (+) | 2.93 | 2.20 | 1.12 | 0.78 |
2 | crystal violet (pKa = +0.8) yellow in acid forms blue in the base form | blue to all catalysts (−) | no color change | no color change | no color change | no color change |
3 | p-nitro chlorobenzene (pKa = −12.70) yellow in acid forms colorless in the base form | colorless to all catalysts (−) | no color change | no color change | no color change | no color change |