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. 2022 Aug 3;61(32):12625–12634. doi: 10.1021/acs.inorgchem.2c01562

Table 1. Structural Parameters for Complexes 1, 2, and 3a.

  Co–P bond distance (Å)
 P–Co–P bite angle (deg)
 dppv dihedral angle (deg)
 trans-phosphine bond angle (deg)
complex P1 P2 P3 P4 P1/P2 P3/P4 P1/P2 P3/P4 P1/P3 P2/P4
1 2.282 2.281 2.281 2.282 83.45 83.45 1.31 1.31 180 180
2 2.277 2.291 2.314 2.272 82.65 84.21 4.96 3.96 174 171
3 2.332 2.318 2.318 2.332 82.04 82.04 2.65 2.65 180 180
a

For 1, P1 and P3 lie on symmetry elements which make the parameters equivalent.