Table 2. Bismuth-Mediated Two-Step Method for the Fluorination of Arylboronic Acids with 47^a.

^aYields are given for step 1 (isolated) and step 2 (determined by ¹⁹F NMR using 1-fluoro-4-nitrobenzene as internal standard).

^bStep 2 performed in the presence of 5.0 equiv of NaF at 110 °C.

^cIsolated yield by preparative TLC. Products contain trace amounts (<5%) of protodeboronation byproducts.