Table 2. NLLS Analyses Performed on the Nyquist Plots (Figure 2d–f) by Using a Boukamp Tool52,53 (See Table 1 for Samples’ Acronyms).
| material | cell condition | equivalent circuit | R1 [Ω] | R2 [Ω] | R1 + R2 | χ2 |
|---|---|---|---|---|---|---|
| Al | OCV | Re(R1Q1)(R2Q2) | 35.2 ± 2.3 | 13.9 ± 4.6 | 49.1 ± 6.9 | 6 × 10–4 |
| 1 CV cycle | Re(R1Q1)(R2Q2) | 31.2 ± 8.5 | 29.5 ± 8.7 | 60.7 ± 17.2 | 9 × 10–5 | |
| 5 CV cycles | Re(R1Q1)(R2Q2) | 33.0 ± 4.7 | 28.0 ± 5.0 | 61 ± 9.7 | 5 × 10–5 | |
| Al_FLGP_50 | OCV | Re(R1Q1)(R2Q2)Qw | 22.9 ± 0.3 | 6.2 ± 0.4 | 29.1 ± 0.7 | 8 × 10–5 |
| 1 CV cycle | Re(R1Q1)(R2Q2)Qw | 5.9 ± 0.2 | 6.0 ± 0.6 | 11.9 ± 0.8 | 5 × 10–4 | |
| 5 CV cycles | Re(R1Q1)(R2Q2)Qw | 5.9 ± 0.2 | 5.5 ± 0.4 | 11.4 ± 0.6 | 3 × 10–4 | |
| Al_FLGP_60 | OCV | Re(R1Q1)(R2Q2)Qw | 22.4 ± 0.7 | 11.6 ± 1.2 | 34.0 ± 1.9 | 4 × 10–4 |
| 1 CV cycle | Re(R1Q1)(R2Q2)Qw | 3.6 ± 0.2 | 5.9 ± 0.5 | 9.5 ± 0.7 | 5 × 10–4 | |
| 5 CV cycles | Re(R1Q1)(R2Q2)Qw | 3.4 ± 0.2 | 5.2 ± 0.4 | 7.6 ± 0.6 | 5 × 10–4 |