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. 2022 Apr 5;61(21):e202117270. doi: 10.1002/anie.202117270

Figure 1.

Figure 1

The application of ex situ and in situ methods over the years. Left inset: the number of papers in Web of science each year in which “in situ” and “mechanochemistry” are used in the title, abstract, or as keywords. a) First in situ XRD experiment including a commercial instrument adapted for use at the synchrotron; [10] Copyright 2021 Nature Publishing Group. b) Customized milling container with a continuous “probing” ring for enhanced XRD data for neat grinding experiments; [11] Copyright 2017 American Chemical Society. c) The recently optimized sample environment and measuring strategy for XRD data. [12] Copyright 2021 Nature Publishing Group.